"Phase-Change Problems"

Abstracts:

1. SUFFICIENTS CONDITIONS TO OBTAIN A PHASE CHANGE IN A HEAT CONDUCTION PROBLEM WITH A CONVECTIVE BOUNDARY CONDITION

María Cristina Sanziel
Universidad Nacional de Rosario - Argentina
e-mail: sanziel@fceia.unr.edu.ar

We consider a one-dimensional heat conduction problem in a slab of length L, with initial temperature greater than the phase-change temperature. There is a heat flux condition on one of the edges and a convective condition on the other. Through a finite difference method we obtain a discrete problem and we show that the solution of this discrete problem converges to the solution of the discrete problem with temperature condition, when the heat transfer coefficient tends to infinity. We also obtain sufficient conditions in order to have a phase change in the discrete problem.

2. Phase change in metal alloys solidification.

Mabel Azucena Medina
Universidad Nacional de Rosario - Argentina
e-mail: mmedina@fceia.unr.edu.ar

A two-dimensional solidification model which calculates the velocity field of the liquid phase, the temperature, the alloy solute composition and the volume liquid fraction, is presented. The influence of convection on the metal alloy solidification is studied, in particular, on the solute segregation and on the solid-liquid boundary. Electromagnetic body forces are implemented. The equations for conservation of energy with phase change, momentum, and solute are solved by the finite element technique.
It is showed that the action of an electromagnetic field, by controlling the flow, changes the distribution of the solute concentration field and modifies the location of the solid liquid boundary. The prediction of the model is sensitive to mesh sizes.

3. NON-ESSENTIAL BLOW-UP FOR THE SUPERCOOLED STEFAN PROBLEM WITH CYLINDRICAL SYMMETRY

Pedro Roberto Marangunic
Instituto de Matemática “Beppo Levi”
Facultad de Ciencias Exactas, Ingeniería y Agrimensura
Universidad Nacional de Rosario
Av. Pellegrini 250 - (2000) Rosario
E-mail: pmarangu@fceia.unr.edu.ar

By means of the well-known relationship between the one-phase supercooled Stefan problem and that one describing the oxygen diffusion-consumption in living tissues, it is possible to analyze more deeply the solution’s behaviour in cases in which blow-up occurs. This task, either for the one-dimensional case or for plane symmetry, was performed by other authors [1]. Here we do an analogous analysis considering cylindrical symmetry, a more realistic assumption for the blood vessels surrounds. We prove that non-essential blow-up cases are possible, i.e. cases in which the free boundary can actually have isolated singularities although they do not prevent the continuation (with a proper redefinition) of the solution, in order to describe phase change to completion.

For the sake of definiteness, if we have a cylindrical domain given by  , and  h  is a given non-positive function in   (and there it does not vanish identically), we consider the one-phase supercooled Stefan problem in conditions of isolated fixed boundary, i. e. the problem which consists of finding a triple  satisfying the following conditions:

   in              (1.1)

                                                           (1.2)

                                                               (1.3)

                                                                 (1.4)

                                                                (1.5)
As it is known, the transformation   (1.6)

 takes the problem (1.1)-(1.5) into the so-called oxygen diffusion-consumption problem:

   in                   (1.7)

                                     (1.8)

                                              (1.9)

                                            (1.10)

                                             (1.11)

where . On the other hand, the change  takes the second problem into the first one.

Physically, as its analogous version for plane symmetry, the system (1.1)-(1.5) modelizes the solidification of a supercooled liquid (one-phase case). Besides its intrinsic interest as a metaestable phenomenon, this subject is related to a variety of problems, for instance the above cited oxygen diffusion-consumption problem (1.7)-(1.11), or even that corresponding to the filtration of a liquid in a partially saturated porous medium [2].

When problem (1.1)-(1.5) has a solution, it is worth asking about the possibility of continuing the solution to arbitrarily large time intervals. It is well-known that one of the following three cases occurs:

(A)  Global existence: the problem has a solution with arbitrarily large  T ;
(B) Finite time extinction of the liquid phase: there is a constant  such that  ;
(C) Blow-up: there is a constant  such that   and  .

Several papers (see [3]) are devoted to study the relationship between these 3 cases and the problem’s data. There it was obtained that an integral, which involves the initial datum and represents an energy, allows predicting the solution’s type.

Let us notice that in the case (C) the solution is suddenly interrupted because of a singularity of the free boundary. However, in [1] it is considered an idea for the possible continuation of solutions beyond the blow-up time . They put the limit of the temperature (when ) as a new initial temperature, and then they analyze whether the “new” problem (for ) admits a solution or not. In negative (affirmative) case they refer the situation as a proper or essential blow-up (resp. non-essential blow-up). In the affirmative case the solution can be continued beyond , and they explicitly construct a specific example in which the solution exists for all times, but the free boundary has an isolated singularity.

In the present communication we adapt those ideas to our conditions of cylindrical symmetry. First, we prove that if  is nonvoid, necessarily  will “touch” the free boundary after a finite time. Then, we characterize the essential blow-up points as such points in which   meets the free boundary.

By controlling the so-called critical isotherms, we finally provide a specific example of non-essential blow-up. In other words, we prove the existence of data for which we have a blow-up in the problem (1.1)-(1.5) but not in the problem (1.7)-(1.11). Indeed, the last one admits global solution (and obviously the function  is non-negative).

4. NUMERICAL SIMULATION OF A STEFAN PROBLEM FOR PACKAGING SUBSTANCES

Mariela Carina Olguín
Universidad Nacional de Rosario - Argentina
e-mail: mcolguin@fceia.unr.edu.ar

There are a lot of situations, for example the transport of foods products, environment's conditioning, etc, where it is necessary to guarantee temperature and humidity conditions. The use, in the packaging, of substances that present a change of phase in an appropriate range of temperature for a particular problem, could be considered with the object to keep those conditions.

For this reason, in the present work, we analyze the behavior of different substances in order to estimate how long does the substance take to melt it completely. The numeric simulation of the problem is based upon the use of finite difference method of implicit type.

5. The use of phase change materials in thermal building conditioning

Angélica Boucíguez
Universidad Nacional de Salta - Argentina
e-mail: bouciga@unsa.edu.ar

The thermal building conditioning consumes a lot of energy, which is generated by traditional forms. There are several alternatives to reduce this consume, one of them is the use of no conventional energy. Among these the solar energy plays an important role in the thermal conditioning.

The use of phase change materials as an integral part of storage collector walls, provides an interesting alternative in passive solar conditioning of building. They can be used in collector - storage wall, as an adaptation of the classic Trombe wall panels.

The phase change materials can be used together with traditional building materials such as gypsum and concrete, as part of plaster of covering of walls and/or ceiling. Besides, they also can be used in pure state, in storage collector walls.

The substitution of classical walls by phase change materials allows to storage the same or a bigger quantity of energy with smaller weight and volume than those of traditional walls.

These materials will have their melting point at an adequate temperature, into the confort range design.

In the selection of phase change materials it is necessary to consider the following properties:

In the present work, several phase change materials have been evaluated, in particular the organic ones are preferred because they present more stability and no supercooling problems.

At the same time, a simulation numerical model has been made to evaluate the performance of the substance and the amount of heat transfer to the ambient to be conditioned.